Preparation of Optically Pure Tertiary Phosphine Oxides via the Addition of P‑Stereogenic Secondary Phosphine Oxide to Activated Alkenes

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Preparation of Optically Pure Tertiary Phosphine Oxides via the Addition of P‑Stereogenic Secondary Phosphine Oxide to Activated Alkenes

Wang, Ji-Ping; Nie, Shao-Zhen; Zhou, Zhong-Yang; Ye, Jing-Jing; Wen, Jing-Hong; Zhao, Chang-Qiu

Journal of organic chemistry, 09/2016, Letnik: 81, Številka: 17

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Functionalized P,C-stereogenic tertiary phosphine oxides were prepared by the addition of (R P)-menthyl phenylphosphine oxide to activated olefins, in high drP and drC, and were isolated in excellent yields. The reaction was readily catalyzed by Ca(OH)2 or occurred with gentle heating. A wide range of substrates, including vinyl ketones, esters, nitriles, and nitro alkenes, can be used in the reaction.

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Dostop do baze podatkov JCR je dovoljen samo uporabnikom iz Slovenije. Vaš trenutni IP-naslov ni na seznamu dovoljenih za dostop, zato je potrebna avtentikacija z ustreznim računom AAI.

Leto	Faktor vpliva		Izdaja		Kategorija		Razvrstitev
Leto	JCR	SNIP	JCR	SNIP	JCR	SNIP	JCR	SNIP

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