Coring was carried out in a soligenous marsh in the Vosges Mountains in the past mining district of Sainte-Marie-aux-Mines (eastern France). High-resolution palynological, non-pollen-palynomorph, and geochemical analyses were performed along the core. Correlations between the herbal composition of the landscape and trace metals in the core reveal a specific palynological pattern during mining activities. Two main periods of anthropogenic impacts on vegetation and trace metal contamination are shown: during the 16th–17th centuries, for mining and smelting activities, and the beginning of the 20th century, for smelting and the Industrial Revolution. No drastic deforestations occurred near the study site, contrary to historical descriptions and prints of the valley. Controlled forest practices were implemented from the beginning of the record, that is, since cal. AD 1000, so the impact of mining activities seems to be less significant than expected near mining sites. We demonstrate that the minerotrophic characteristics of the record closest to past mining sites allows for (1) the description of the landscape associated with anthropogenic activities and (2) the recording of past trace metal emissions without post-depositional mobility.