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IRIFUNE, T; NISHIYAMA, N; OHTAKA, O; KURODA, K; INOUE, T; ISSHIKI, M; UTSUMI, W; FUNAKOSHI, K.-I; URAKAWA, S; UCHIDA, T; KATSURA, T
Science (American Association for the Advancement of Science), 03/1998, Letnik: 279, Številka: 5357Journal Article
The phase boundary between spinel (gamma phase) and MgSiO3 perovskite + MgO periclase in Mg2SiO4 was determined by in situ x-ray measurements by a combination of the synchrotron radiation source (SPring-8) and a large multianvil high-pressure apparatus. The boundary was determined at temperatures between 1400 degrees to 1800 degreesC, demonstrating that the postspinel phase boundary has a negative Clapeyron slope as estimated by quench experiments and thermodynamic analyses. The boundary was located at 21.1 (+/-0.2) gigapascals, at 1600 degreesC, which is approximately 2 gigapascals lower than earlier estimates based on other high-pressure studies.
