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Guimond, Sébastien; Wertheimer, Michael R.
Journal of applied polymer science, 5 November 2004, Letnik: 94, Številka: 3Journal Article
The surface degradation and production of low molecular weight oxidized materials (LMWOM) on biaxially oriented polypropylene (BOPP) and low‐density polyethylene (LDPE) films was investigated and compared for two different dielectric barrier discharge (DBD) treatment types, namely air corona and nitrogen atmospheric pressure glow discharge (N2 APGD). Contact angle measurements, X‐ray photoelectron spectroscopy (XPS), and atomic force microscopy (AFM) analyses were performed in conjunction with rinsing the treated films in water. It is shown that N2 APGD treatments of both polyolefins result in much less surface degradation, therefore, allowing for a significantly higher degree of functionalization and better wettability. Hydrophobic recovery of the treated films has also been studied by monitoring their surface energy (γs) over a period of time extending up to several months after treatment. Following both surface modification techniques, the treated polyolefin films were both found to undergo hydrophobic recovery; however, for N2 APGD modified surfaces, γs ceases to decrease after a few days and attains a higher stable value than in the case of air corona treated films. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 1291–1303, 2004
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