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Zhang, Yajing; Sun, Youwen; Chen, Bin; Xu, Meichen; Li, Chen; Zhang, Dayong; Zhang, Guozhu
Organic letters, 02/2020, Letnik: 22, Številka: 4Journal Article
A photoinduced, copper-catalyzed, highly enantioselective dual alkylation/arylation and alkynylation of alkene is reported. A single chiral copper(I) complex serves to enable photoredox catalysis and induce enantioselectivity during the reaction. This reaction couples three different components under mild reaction conditions, exhibits a broad substrate scope, and provides facile access to chiral propargylic systems, including those featuring valuable fluorinated substituents.
