At present, the use of microstructure to change the optical properties and wetting properties of the material itself has become the main means to improve the utilization rate of materials in the manufacturing industry. Due to the hydrophilicity of the material surface can achieve underwater self-cleaning, directional transportation function, it becomes an indispensable part of surface modification. Water jet-guide laser processing can significantly reduce the formation of the heat-affected zone and crack, and can clearly ablate the material, with higher precision and resolution. In this experiment, the effects of scan spacing, laser output power and channel aspect ratio are examined and processing conditions for achieving near superhydrophilicity are provided. Owing to the anaerobic processing environment, the surface chemical composition of the material does not change, and the hydrophilicity is increased by 8% to 43% compared with that before. Increasing the aspect ratio can increase the wettability, when the aspect ratio is more than 1.63, the wettability begins to rebound, and the wettability becomes worse. Using small laser power and multiple scanning processing scheme can make the surface covered with tiny small pillars of micro-nano particles layer beneficial to increase the droplet adhesion, and the minimum contact angle can reach 37.2°.