•MOFs with different dimensionalities are a versatile host platform for the effective enzymes immobilization.•Dimensionality of MOFs significantly affects performance of enzyme@MOF composites.•Preparation approaches of enzyme@MOF composites with different dimensionalities are evaluated.•There will be great demand on enzyme@MOF composites with diverse functionality. Metal-organic frameworks (MOFs) are an emerging class of porous materials with well-defined pore and crystal structure, favorable biocompatibility, good chemo-/machinal stability and high surface area, which endow them as ideal host matrix to develop enzyme@MOF composites. Most of the enzyme@MOF composites exhibit excellent catalysis performances performance and increased stability. In the past decade, many efforts have been made to develop enzyme@MOF composites with potential applications. The dimensionality of the MOFs has a significant effect on the catalytic performance of enzyme@MOF composites. However, there have been few reviews on enzyme@MOF composites with different dimensionalities. This review aims to describe the contemporary advances in the development of enzyme@MOF composites with different dimensionalities. Synthesizing strategies of enzyme@MOF composites with different dimensionalities are summarized. The interaction between enzymes and MOFs with different dimensionalities from the aspects of activity, stability, and reusability are discussed. Furthermore, the application and potential research direction of enzyme@MOF composites are introduced. We believe this work will be helpful for readers to understand the fundamental research and applications of enzyme@MOF composites with different dimensionalities.