Cyclization Reaction of Donor–Acceptor Oxiranes with N,N′-Disubstituted Thioureas: A Domino Process to trans-Dihydropyrimidines

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Cyclization Reaction of Donor–Acceptor Oxiranes with N,N′-Disubstituted Thioureas: A Domino Process to trans-Dihydropyrimidines

Wang, Jing; Zhang, Qi-Ying; Xie, Ming-Sheng; Wang, Dong-Chao; Qu, Gui-Rong; Guo, Hai-Ming

Organic letters, 10/2018, Letnik: 20, Številka: 20

Journal Article

An unprecedented cyclization reaction of donor–acceptor oxiranes with N,N′-disubstituted thioureas to construct trans-dihydropyrimidines is presented. Preliminary reaction mechanism studies demonstrated that the reaction underwent sequential cycloaddition/amine ester exchange/oxygen–sulfur exchange/desulfuration/Michael addition process. A wide range of trans-dihydropyrimidines were produced with high yields up to 94% by using this method.

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Leto	Faktor vpliva		Izdaja		Kategorija		Razvrstitev
Leto	JCR	SNIP	JCR	SNIP	JCR	SNIP	JCR	SNIP

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