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  • Ternary Recombination of H3...
    Johnsen, R; Rubovič, P; Dohnal, P; Hejduk, M; Plašil, R; Glosík, J

    The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory, 10/2013, Letnik: 117, Številka: 39
    Journal Article

    We present results of plasma afterglow experiments on ternary electron-ion recombination rate coefficients of H3 + and D3 + ions at temperatures from 50 to 300 K and compare them to possible three-body reaction mechanisms. Resonant electron capture into H3* Rydberg states is likely to be the first step in the ternary recombination, rather than third-body-assisted capture. Subsequent interactions of the Rydberg molecules with ambient neutral and charged particles provide the rate-limiting step that completes the recombination. A semiquantitative model is proposed that reconciles several previously discrepant experimental observations. A rigorous treatment of the problem will require additional theoretical work and experimental investigations.