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Metikos-Hukovic, Mirjana; Grubac, Zoran; Omanovic, Sasha
Journal of the Serbian Chemical Society, 2013, Letnik: 78, Številka: 12Journal Article
The electrochemically-assisted modification of the N-austenitic stainless steel (ASS N25) surface was successfully employed to improve barrier properties of the passive film in a chloride containing solution. The chemical composition, electronic and barrier properties of the surface film before and after the electrochemical treatment were examined using X-ray photoelectron spectroscopy (XPS) and electrochemical impedance spectroscopy (EIS). Electrochemical measurements were carried out in a corrosion testing solution. The excellent corrosion resistance (both pitting and general) of the N-steel?s modified surface was discussed according to the Mott-Schottky analysis of the interfacial capacitance of the space charge layer and EIS results. The conductivity change of the surface film from an n- to a p-type in the pitting susceptible region was explained using the XPS analysis and semiconducting properties of the film. nema
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Leto | Faktor vpliva | Izdaja | Kategorija | Razvrstitev | ||||
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JCR | SNIP | JCR | SNIP | JCR | SNIP | JCR | SNIP |
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Vir: Osebne bibliografije
in: SICRIS
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