A strong and tough self-healing elastomer is prepared based on double reversible networks consisting of ionic interactions and Diels-Alder (D-A) crosslinks. The elastomer is synthesized through one-pot copolymerization of a pair of oppositely charged monomers and furan functionalized methacrylate (FMA), which is then crosslinked with 1,1'-(Methylenebis(4,1-phenylene))bis(1H-pyrrole-2,5-dione) (BMI) via Diels-Alder (D-A) reaction. The oppositely charged monomers form ionic bonds which can segregate into aggregates with a wide distribution of size. Under heating or external force, the aggregates can dissociate from small to big ones to dissipate amount of energy and endow the materials with high mechanical properties (13 MPa in strength, 480% in stretchability). While the D-A crosslinks act as covalent bonds at room temperature and endow the materials with high elasticity and fast shape recovery ability. These two reversible networks with different dynamics contribute to the multi-scale self-healing properties of the elastomer. As a result, the self-healing efficiency of the elastomer is as high as 86%. A strong and tough self-healing elastomer with high mechanical properties (13 MPa in fracture strength, 480% in stretchability) and self-healing efficiency (86%) is prepared based on double reversible networks consisting of ionic interactions and Diels-Alder (D-A) crosslinks. Display omitted •The elastomers have high mechanical properties (13 MPa in fracture strength, 480% in stretchability) and self-healing efficiency (86%).•The ionic aggregates have wide size distribution which can desegregate progressively to dissipate energy.•The D-A crosslinks endow the sample with fast recovery ability.•The ionic bonds are dynamic at room temperature while the D-A crosslinks are dynamic at high temperature.