•Fe-5Ti alloys (d = 100–125 µm) after nitrogen trapping in lithium were investigated.•Nitrogen is trapped on the surfaces of Fe-5Ti immediately in the immersion tests.•Nitrogen diffusion in Fe-5Ti is much faster than in titanium. Liquid lithium, a candidate material for the target of International Fusion Material Irradiation Facility (IFMIF), easily contains nitrogen. Nitrogen in liquid lithium should be removed as it accelerates corrosion of tubing materials. Hot trapping by iron-titanium alloys is expected to be a practical method. In order to understand the characteristics of nitrogen trapping with iron-titanium alloys in liquid lithium, nitrogen distribution was observed by Soft X-ray Emission Spectroscopy (SXES). Samples of Fe-5Ti alloys were immersed for 9–256 h in liquid lithium which contains 1000 w-ppm of nitrogen at 823 K and studied by X-ray Powder diffraction and SXES. The results show that nitrogen is trapped mainly in the grain boundaries and on the surfaces of the Fe-5Ti alloys and diffuses in Fe-5Ti much faster than in pure titanium. In addition, it is assumed that the amount of nitrogen trapping by the surface of Fe-5Ti alloys does not depend on the immersion time.