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Gil-San-Millan, Rodrigo; López-Maya, Elena; Platero-Prats, Ana E; Torres-Pérez, Virginia; Delgado, Pedro; Augustyniak, Adam W; Kim, Min Kun; Lee, Hae Wan; Ryu, Sam Gon; Navarro, Jorge A. R
Journal of the American Chemical Society, 07/2019, Letnik: 141, Številka: 30Journal Article
UiO-66, MOF-808 and NU-1000 metal–organic frameworks exhibit a differentiated reactivity toward Mg(OMe)2(MeOH)24 related to their pore accessibility. Microporous UiO-66 remains unchanged while mesoporous MOF-808 and hierarchical micro/mesoporous NU-1000 materials yield doped systems containing exposed MgZr5O2(OH)6 clusters in the mesoporous cavities. This modification is responsible for a remarkable enhancement of the catalytic activity toward the hydrolytic degradation of P–F and P–S bonds of toxic nerve agents, at room temperature, in unbuffered aqueous solutions.
