The development of flexible zinc‐air batteries (FZABs) has attracted broad attention in the field of wearable electronic devices. Gel electrolyte is one of the most important components in FZABs, which is urgent to be optimized to match with Zn anode and adapt to severe climates. In this work, a polarized gel electrolyte of polyacrylamide‐sodium citric (PAM‐SC) is designed for FZABs, in which the SC molecules contain large amount of polarized −COO− functional groups. The polarized −COO− groups can form an electrical field between gel electrolyte and Zn anode to suppress Zn dendrite growth. Besides, the −COO− groups in PAM‐SC can fix H2O molecules, which prevents water from freezing and evaporating. The polarized PAM‐SC hydrogel delivers a high ionic conductivity of 324.68 mS cm−1 and water retention of 96.85 % after being exposed for 96 h. FZABs with the PAM‐SC gel electrolyte exhibit long cycling life of 700 cycles at −40 °C, showing the application prospect under extreme conditions. A polarized gel electrolyte of polyacrylamide‐sodium citric (PAM‐SC) is synthesized for flexible zinc‐air batteries. The polarized −COO− functional groups in gel electrolyte not only form an electrical field to suppress Zn dendrite growth, but also prevent water from freezing and evaporating. The FZABs with the PAM‐SC gel electrolyte exhibit long cycling life of 700 cycles at −40 °C, showing the application prospect under extreme conditions.