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da Rosa, Rafaela R.; Silva, Pedro E. S.; Saraiva, Diogo V.; Kumar, Anant; Sousa, António P. Mendes; Sebastião, Pedro; Fernandes, Susete N.; Godinho, Maria Helena
Advanced materials (Weinheim), 07/2022, Letnik: 34, Številka: 28Journal Article
The colloidal suspensions of aqueous cellulose nanocrystals (CNCs) are known to form liquid crystalline (LC) systems above certain critical concentrations. From an isotropic phase, tactoid formation, growth, and sedimentation have been determined as the genesis of a high‐density cholesteric phase, which, after drying, originates solid iridescent films. Herein, the coexistence of a liquid crystal upper phase and an isotropic bottom phase in CNC aqueous suspensions at the isotropic–nematic phase separation is reported. Furthermore, isotropic spindle‐like domains are observed in the low‐density LC phase and high‐density LC phases are also prepared. The CNCs isolated from the low‐ and high‐density LC phases are found to have similar average lengths, diameters, and surface charges. The existence of an LC low‐density phase is explained by the presence of air dissolved in the water present within the CNCs. The air dissolves out when the water solidifies into ice and remains within the CNCs. The self‐adjustment of the cellulose chain conformation enables the entrapment of air within the CNCs and CNC buoyancy in aqueous suspensions. A new low‐density liquid crystalline (LC) phase in aqueous colloidal suspensions of rod‐like cellulose nanocrystals (CNCs) is demonstrated. This behavior is an indication that the LC phase is an indirect way to reveal CNCs/water interactions. The scale bar in the image is 100 µm.
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