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  • Proto-Calcite and Proto-Vat...
    Gebauer, Denis; Gunawidjaja, Philips N.; Ko, J. Y. Peter; Bacsik, Zoltán; Aziz, Baroz; Liu, Lijia; Hu, Yongfeng; Bergström, Lennart; Tai, Cheuk-Wai; Sham, Tsun-Kong; Edén, Mattias; Hedin, Niklas

    Angewandte Chemie (International ed.), November 15, 2010, Letnik: 49, Številka: 47
    Journal Article

    Amorphous order: Amorphous calcium carbonates (ACC) have an intrinsic structure relating to the crystalline polymorphs of calcite and vaterite. The proto‐crystalline structures of calcite and vaterite (pc‐ACC and pv‐ACC) are analyzed by NMR (see picture), IR, and EXAFS spectroscopy, which shows that the structuring of ACC relates to the underlying pH‐dependent equilibria.