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Wang, Min‐Qiang; Ye, Cui; Liu, Heng; Xu, Maowen; Bao, Shu‐Juan
Angewandte Chemie International Edition, February 12, 2018, Letnik: 57, Številka: 7Journal Article
Transition‐metal phosphides (TMPs) have emerged as promising catalyst candidates for the hydrogen evolution reaction (HER). Although numerous methods have been investigated to obtain TMPs, most rely on traditional synthetic methods that produce materials that are inherently deficient with respect to electrical conductivity. An electrospinning‐based reduction approach is presented, which generates nickel phosphide nanoparticles in N‐doped porous carbon nanofibers (Ni2P@NPCNFs) in situ. Ni2P nanoparticles are protected from irreversible fusion and aggregation in subsequent high‐temperature pyrolysis. The resistivity of Ni2P@NPCNFs (5.34 Ω cm) is greatly decreased by 104 times compared to Ni2P (>104 Ω cm) because N‐doped carbon NFs are incorporated. As an electrocatalyst for HER, Ni2P@NPCNFs reveal remarkable performance compared to other previously reported catalysts in acidic media. Additionally, it offers excellent catalytic ability and durability in both neutral and basic media. Encouraged by the excellent electrocatalytic performance of Ni2P@NPCNFs, a series of pea‐like MxP@NPCNFs, including Fe2P@NPCNFs, Co2P@NPCNFs, and Cu3P@NPCNFs, were synthesized by the same method. Detailed characterization suggests that the newly developed method could render combinations of ultrafine metal phosphides with porous carbon accessible; thereby, extending opportunities in electrocatalytic applications. Like peas in a pod: An electrospinning‐based reduction approach was used to embed metal phosphide nanoparticles in nitrogen‐doped porous carbon nanofibers (NPCNFs). A series of pea‐like MxP@NPCNFs structures were fabricated (MxP=Ni2P, Fe2P, Co2P, and Cu3P). Ni2P@NPCNFs is a highly active catalyst for the hydrogen evolution reaction at all pH values.
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