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Yang, Li‐Miao; Li, Shan‐Shan; Zhang, You‐Ya; Lu, Jin‐Liang; Deng, Jing‐Tong; Ma, Ai‐Jun; Zhang, Xiang‐Zhi; Zhang, Shu‐Yu; Peng, Jin‐Bao
Advanced synthesis & catalysis, April 13, 2021, Letnik: 363, Številka: 8Journal Article
A palladium catalyzed reductive aminocarbonylation of benzylic ammonium triflates with nitroarenes for the synthesis of phenylacetamides was developed. Using Pd(acac)2/DPPF catalyst system, a range of different substituted phenylacetamides were prepared in moderate to good yields from benzylic ammonium triflates and nitroarenes through Csp3−N bond cleavage. A variety of alkyl, aryl, and halide substituents on both substrates can be used, and many useful functional groups can be tolerated.
