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Fan, Duona; Sabri, Ahmed; Sasai, Hiroaki; Takizawa, Shinobu
Molecules (Basel, Switzerland), 2023-Jan-01, 2023-01-01, 20230101, Letnik: 28, Številka: 1Journal Article
This study processes a facile and green approach for the Markovnikov-selective hydroamination of styrene with naphthylamine through irradiation with UV LED light (365 nm) via an electron donor-acceptor complexation between naphthylamines and oxygen in situ. This protocol showcases the synthetic potential for aerobic C-N bond formation without using a metal catalyst and photosensitizer. Three naphthylamines were examined and afforded desired C-N bond formation product in moderate yield.
