A novel interferometric method is presented for the measurement of the absolute energy of electron beams. In the year 2016, a pioneering experiment was performed using a 195 MeV beam of the Mainz Microtron (MAMI). The experimental setup consisted of two collinear magnetic undulators as sources of coherent optical synchrotron light and a high-resolving grating monochromator. Beam energy measurements required the variation of the relative undulator distance in the decimeter range and the analysis of the intensity oscillation length in the interference spectrum. A statistical precision of 1 keV was achieved in 1 h of data taking, while systematic uncertainties of 700 keV were present in the experiment. These developments aim for a relative precision of 10−5 in the absolute momentum calibrations of spectrometers and high-precision hypernuclear experiments. Other electron accelerators with beam energies in this regime such as the Mainz Energy Recovering Superconducting Accelerator (MESA) might benefit from this new method.