We estimate the spectral index, beta , of polarized synchrotron emission as observed in the 9 yr Wilkinson Microwave Anisotropy Probe sky maps using two methods, linear regression ("T-T plot") and maximum likelihood. We partition the sky into 24 disjoint sky regions and evaluate the spectral index for all polarization angles between 0degrees and 85degrees in steps of 5degrees.Averaging over polarization angles,we derive a mean spectral index of beta super(all-sky) = -2.99+ or -0.01 in the frequency range of 23-33 GHz. We find that the synchrotron spectral index steepens by 0.14 from low to high Galactic latitudes, in agreement with previous studies, with mean spectral indices of beta super(plane) = -2.98 + or - 0.01 and beta super(high-lat) = -3.12 + or - 0.04. In addition, we find a significant longitudinal variation along the Galactic plane with a steeper spectral index toward the Galactic center and anticenter than toward the Galactic spiral arms. This can be well modeled by an offset sinusoidal, beta (l) = -2.85 + 0.17 sin(2l - 90degrees). Finally, we study synchrotron emission in the BICEP2 field, in an attempt to understand whether the claimed detection of large-scale B-mode polarization could be explained in terms of synchrotron contamination. Adopting a spectral index of beta = -3.12, typical for high Galactic latitudes, we find that the most likely bias corresponds to about 2% of the reported signal (r = 0.003). The flattest index allowed by the data in this region is beta = -2.5, and under the assumption of a straight power-law frequency spectrum, we find that synchrotron emission can account for at most 20% of the reported BICEP2 signal.