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Zou, Keyong; Miller, W. Todd; Givens, Richard S.; Bayley, Hagan
Angewandte Chemie (International ed.), August 17, 2001, Letnik: 40, Številka: 16Journal Article
Caged but not trapped! Caged reagents are molecules from which biological effectors are released by photolysis. Here, p‐hydroxyphenacyl bromide is used to derivatize a model peptide containing a thiophosphotyrosine residue in order to mimic phosphorylation at tyrosine. Upon photolysis, a biologically active peptide is released. Peptides and proteins caged on thiophosphotyrosine will be useful in signal transduction research.
