It is expected that specific globular clusters (GCs) can contain up to a hundred of millisecond pulsars. These pulsars can accelerate leptons at the shock waves originated in collisions of the pulsar winds and/or inside the pulsar magnetospheres. Energetic leptons diffuse gradually through the GC Comptonizing stellar and microwave background radiation. We calculate the GeV–TeV γ-ray spectra for different models of injection of leptons and parameters of the GCs assuming reasonable, of the order of 1 per cent, efficiency of energy conversion from the pulsar winds into the relativistic leptons. It is concluded that leptons accelerated in the GC cores should produce well localized γ-ray sources which are concentric with these GCs. The results are shown for four specific GCs (47 Tuc, Ter 5, M13 and M15), in which significant population of millisecond pulsars have been already discovered. We argue that the best candidates, which might be potentially detected by the present Cherenkov telescopes and the planned satellite telescopes (AGILE, GLAST), are 47 Tuc on the Southern hemisphere, and M13 on the Northern hemisphere. We conclude that detection (or non-detection) of GeV–TeV γ-ray emission from GCs by these instruments put important constraints on the models of acceleration of leptons by millisecond pulsars.