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  • Ultrasonic-assisted pulse e...
    Nasirpouri, Farzad; Farmani, Amirali; Safarpour, Saeid

    Surface & coatings technology, 07/2024, Letnik: 487
    Journal Article

    Ultrasonic-assisted pulse electrodeposition of nanocrystalline nickel (NC-Ni) coatings from Watts bath on copper substrate was investigated. Direct (DC), pulsed (PC), and pulse reversed (PRC) current electrodeposition techniques were employed to electrodeposit NC-Ni coatings in the absence and presence of ultrasound wave with a nominal power ranging from 95 W to 200 W and their surface morphology, hardness, and crystalline microstructure were compared. We observed that as the ultrasound power increases, the cathodic efficiency and the microhardness increase, whereas the crystallite size and surface roughness decrease for NC-Ni electrodeposited by the three techniques in the same way. However, the effect of pulse waveform is dominant. The finest crystallite size (24 nm) and highest hardness (585 HV) were achieved for NC Ni coatings PC electrodeposited using an ultrasound with 200 W nominal power. It is believed that the coating produced by PC and PRC techniques develops a preferential orientation in (111) and (100) planes, respectively. The application of ultrasound wave and increasing its nominal power changes the preferential orientation of all obtained coatings to (111) planes. The corrosion behavior of NC Ni coatings, as investigated by potentiodynamic polarization and electrochemical impedance spectroscopy in NaOH solution, demonstrates the effect of nanocrystalline on the passivation and corrosion resistance of NC-Ni coatings. •Ultrasonic-assisted pulse electrodeposition of nanocrystalline nickel (NC-Ni) coatings from Watts bath was exploited.•Effect of ultrasound wave with different nominal power ranging from 95 W to 200 W was studied.•Effect of direct, pulse and pulse-reverse current on nucleation and growth of nickel films was studied.•Increasing ultrasound power boosts cathodic efficiency and microhardness while decreasing crystallite size and surface roughness.•NC Ni coatings in NaOH solution show that corrosion behavior is influenced by crystallite size and morphology