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Uporaba ciklodekstrinov v sintezi optično aktivnih snovi = Use of cyclodextrins in synthesis of optically active compounds
Verhnjak, Katarina, 1965- ; Urleb, Uroš
V članku podajamo pregled uporabe ciklodekstrinov v asimetrični sintezi. Ciklodekstrine uporabljajo v sintezi optično aktivnih učinkovin kot katalizatorje in/ali induktorje kiralnosti v molekulah. ...Katalizatorji so predvsem pri hidrolizah estrov in amidov, kjer lahko selektivno pospešijo nastanek enega enantiomera. Kot induktorje kiralnosti v molekulah so jih uporabili pri mnogih redukcijah, oksidacijah in adicijah prokiralnih spojin.
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