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A carbonate-templated decanuclear mn nanocage with two different silsesquioxane ligandsSheng, Kai ...The mild reaction of the preorganized silsesquioxane precursor with Mn(II) acetate under ambient conditions results in a mixed-valent {MnII 6MnIII4} nanocage (SD/Mn10) which is protected by both ... acyclic trimer [Si3] and cyclic tetramer [Si4]. Serendipitous capture of atmospheric CO2 as a μ5-carbonate anion placed at the center supports the formation of the cluster. The magnetic analysis reveals the strong antiferromagnetic interactions between Mn ions. Moreover, the dropcasting film of SD/Mn10 shows photoelectric activity indicating its great potential as a semiconductor for photoelectric conversion applications.Source: Inorganic chemistry. - ISSN 0020-1669 (Vol. 60, no. 19, 2021, str. 14866-14871)Type of material - article, component part ; adult, seriousPublish date - 2021Language - englishCOBISS.SI-ID - 124948227
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Database name | Field | Year |
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Links to authors' personal bibliographies | Links to information on researchers in the SICRIS system |
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Sheng, Kai | |
Wang, Ran | |
Tang, Xinde | |
Jagodič, Marko, 1981- | 28581 |
Jagličić, Zvonko | 11892 |
Pang, Laixue | |
Dou, Jian-Min | |
Gao, Zhi-Yong | |
Feng, Hua-Yu | |
Tung, Chen-Ho | |
Sun, Di |
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