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Colloidal templating
Cameron, Neil R. ; Krajnc, Peter, 1970- ; Silverstein, Michael S.
This chapter describes the use of colloidal systems, including emulsion droplets, bicontinuous microemulsion channels, water droplets, and solid particles, as templates to create porous polymer ...materials (Fig. 4.1). Conceptually, the process is general to all types of colloidal dispersion: A biphasic system is created, and the continuous phase (or, in the case of bicontinuous microemulsions, one of the co-continuous phases) is polymerized. The colloidal entities, which are removed following polymerization, thus serveto create porosity in the final polymeric material. Depending on the nature of the colloidal system employed, the characteristic domain size of the porous network can range from a few nanometers to hundreds of micrometers.
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