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Loss of oxygen atoms on well-oxidized cobalt by heterogeneous surface recombinationPaul, Domen ...Calorimetry is a commonly used method in plasma characterization, but the accuracy of the method is tied to the accuracy of the recombination coefficient, which in turn depends on a number of surface ... effects. Surface effects also govern the kinetics in advanced methods such as atomic layer oxidation of inorganic materials and functionalization of organic materials. The flux of the reactive oxygen atoms for the controlled oxidation of such materials depends on the recombination coefficient of materials placed into the reaction chamber, which in turn depends on the surface morphology, temperature, and pressure in the processing chamber. The recombination coefficient of a well-oxidized cobalt surface was studied systematically in a range of temperatures from 300 to 800 K and pressures from 40 to 200 Pa. The coefficient increased monotonously with decreasing pressure and increasing temperature. The lowest value was about 0.05, and the highest was about 0.30. These values were measured for cobalt foils previously oxidized with oxygen plasma at the temperature of 1300 K. The oxidation caused a rich morphology with an average roughness as deduced from atomic force images of 0.9 µm. The results were compared with literature data, and the discrepancy between results reported by different authors was explained by taking into account the peculiarities of their experimental conditions.Source: Materials [Elektronski vir]. - ISSN 1996-1944 (Vol. 16, iss. 17, 2023, 1-14 str.)Type of material - e-article ; adult, seriousPublish date - 2023Language - englishCOBISS.SI-ID - 162250755
Author
Paul, Domen |
Mozetič, Miran, 1961- |
Zaplotnik, Rok, 1981- |
Ekar, Jernej |
Vesel, Alenka |
Primc, Gregor, 1984- |
Đonlagić, Denis
Topics
materiali |
preizkušanje |
kinetika |
organski materiali
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Author | Paul, Domen ... |
Title | Loss of oxygen atoms on well-oxidized cobalt by heterogeneous surface recombination |
Publication date | 2023-08-24 |
COBISS.SI-ID | 162250755 |
Publication version in repository | Publisher's version |
Publication licence | Creative Commons Attribution 4.0 International |
Embargo | Immediate publication for public |
Project(s) from which the publication was funded
Title | Acronym | Project ID | Funder |
---|---|---|---|
Tankoplastne strukture in plazemsko inženirstvo površin | P2-0082-2022 |
Javna agencija za znanstvenoraziskovalno in inovacijsko dejavnost Republike Slovenije |
|
Miniaturni optični-vlakenski senzorji prostih radikalov za nadzor plazemskih procesov | L2-4487-2022 |
Javna agencija za znanstvenoraziskovalno in inovacijsko dejavnost Republike Slovenije |
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Database name | Field | Year |
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Links to authors' personal bibliographies | Links to information on researchers in the SICRIS system |
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Paul, Domen | 52423 |
Mozetič, Miran, 1961- | 10429 |
Zaplotnik, Rok, 1981- | 31618 |
Ekar, Jernej | 53529 |
Vesel, Alenka | 20048 |
Primc, Gregor, 1984- | 33326 |
Đonlagić, Denis | 15006 |
Source: Personal bibliographies
and: SICRIS
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