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PolyHIPEs from methyl methacrylate : hierarchically structured microcellular polymers with exceptional mechanical propertiesHuš, Sebastjan ; Krajnc, Peter, 1970-Highly porous monoliths with excellent mechanical properties and porosity of up to 90% were prepared by the polymerisation of high internal phase emulsions (HIPE) containing methyl methacrylate (MMA) ... and ethylene glycol dimethacrylate (EGDMA). Materials with open cellular morphology and cavity diameters between 0.6 and 4.5 %m are obtained using a homogenizer and between 0.8 and 25 %m using a standard overhead stirrer. Samples with 80% pore volume have E-moduli up to 180 MPa, while 75% porous samples exhibit E-moduli up to 211 MPa. A dependence of mechanical properties on cavity size distribution is identified, where a more hierarchically developed porous structure results in significantly better mechanical properties.Source: Polymer. - ISSN 0032-3861 (Vol. 55, iss. 17, Avg. 2014, str. 4420-4424)Type of material - article, component partPublish date - 2014Language - englishCOBISS.SI-ID - 17975574
Author
Huš, Sebastjan |
Krajnc, Peter, 1970-
Topics
porous copolymers |
methyl methacrylate |
polyHIPE |
porous polymers
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Huš, Sebastjan | 35033 |
Krajnc, Peter, 1970- | 15501 |
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