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Navidezni molski volumni nekaterih komponent sadnih arom v raztopini ogljikovega tetraklorida pri temperaturi 298 K : magistrsko delo = Apparent molal volumes of some components of fruit aroma in dilute carbon tetrachloride solution 298 K : master of science thesis
Jurca, Sabina
Določila sem gostote raztopinam etil-2-metil butanoata, 3-heksen-1-ola, 2-heksenala, etil dekanoata, metil antranilata, anetola, damascenona in izoamil propionata v ogljikovem tetrakloridu do ...koncentracije 4,0 mol ▫$dm^-3$▫ pri temperaturi 298 K. Na osnovi teh podatkov sem izračunala navidezne molske volumne in parcialne molske volumne topljenca in topila. Ugotovila sem, da je parcialni presežni volumen topljenca relativno majhen in pozitiven. Iz razmerja molskega in van der Waalsovega volumna sem ugotovila, da se preiskovalni topljenci obnašajo kot sorazmerno nepolarne spojine. Parcialni molski volumen topljenca pri neskončnem razredčenju sem obravnavala z modelom toge krogle. Neidealno obnašanje sistemov sem analizirala s presežnim volumnom raztopine na kilogram topila tako da sem po McMillan-Mayerjevi teoriji izračunala virialne koeficiente.
Type of material - master's thesis
Publication and manufacture - Ljubljana : [S. Jurca], 1996
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