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The role of the solvent on the dimensionality of the Mg-MOF investigated by NMR spectroscopy [Elektronski vir]
Rangus, Mojca, 1978- ...
Hybrid inorganic-organic coordination polymers or metal-organic framework (MOF) materials represent an extensive group of materials where inorganic building units are interconnected through rigid ...organic molecules (typically polycarboxylates) forming crystalline structure. In the last decade theyhave been growing increasingly popular because of their vast potential in a variety of applications such as heterogeneous catalysis, ion exchange, gas separation and storage, heat storage and drug delivery. In an attempt to synthesise new structures, the emphasis was also put on the variation of the solvent. The influence the solvent has on the structure and dimensionality wasstudied previously and it was determined that the solvent can play an important role in the structure formation. In this work we discuss the role of the solvent on the structure and formation of some new magnesium tricarboxylate phases.
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