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13.
Sinteza polimerov za pripravo membran
Stropnik, Črtomir
Predstavljen je matematični model za postopek fazne inverzije, ki je najpomembnejša metoda za pripro sintetičnih asimetričnih polimernih membran z opno. Proučene so zakonistosti ternernega faznega ...diagrama za sistem polimer/topilo/netopilo iz eksperimentalnega in računsko-teoretičnega stališča. Iz fenomenoloških enačb e izpeljana difuzijska enačba za transport snovi v raztooini polimera, za transport snovi v koagulacijski kopeli pa je uporabljen modificiran Fick-ov zakon. Model omogoča racionalizacijo "poti fazne inverzije" v ternarnem faznemdiagramu in racionalizacijo povezav med pogoji priprave asimetrične membrane in njenimi permselektivnimi lastnostmi.
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