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Nucleation and growth of a passive film on AISI 420 martensitic stainless steel under potentiostatic conditionsFuchs-Godec, Regina ; Petek, Aljana ; Doleček, ValterThe kinetics of the early stage s of passive film formation on AISI stainless stell in mixtures of 0.1M ▫$H_2$▫S▫$O_4$▫ and 0.1M N▫$a_2$▫S▫$O_4$▫, with pH-values of 2.42, 2.85 and 3.33, were studied ... at different anodic potentials. The potentiostatic step method was used as an electrochemical technique in which the anodic current density was measured as a function of time. For analysis of the measured data, the theory of "topochemical reaction" was applied for the charcterization of the exponent n in that part where the stepest current decay was observed. Through this theory, which includes the Erofeev equation, the number of conversion steps could be obtained, as well as the numebr of directions in which the nuclei grow. It was found that this theory can be sucessfully applied to the passivation process of AISI 420 stainles steel.Source: Acta chimica slovenica. - ISSN 1318-0207 (Vol. 49, no. 1, mar. 2002, str. 139-148)Type of material - article, component partPublish date - 2002Language - englishCOBISS.SI-ID - 6971158
Author
Fuchs-Godec, Regina |
Petek, Aljana |
Doleček, Valter
Topics
korozija |
korozijska odpornost |
martenzitna nerjavna jekla |
pasivni film |
potenciostatična koračna metoda |
topokemijske reakcije |
corrosion |
corrision resistance |
martensitic stainless steels |
passive films |
potentiostatic step method |
topochemical reactions
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Database name | Field | Year |
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Fuchs-Godec, Regina | 08762 |
Petek, Aljana | 08264 |
Doleček, Valter | 00869 |
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