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Vpliv temperature in koncentracije kloridnih ionov na razvoj točkaste korozije avstenitnega jekla AISI 304 L v 0.5 M ▫$H_2$▫▫$SO_4$▫Fuchs-Godec, ReginaProučevali smo korozijsko odpornost avstenitnega jekla AISI 304L v vodnih raztopinah 0,5 M H2SO4 + 0,01 M KCNS + x M NaCl pri temperaturah 25, 40, in 50 °C. Kritično koncentracijo kloridnih ionov ... (CIC), ter kritično temperaturo (CPT) potrebno za začetek točkaste korozije, smo določili na podlagi parametrov odčitanih iz potenciodinamskih polarizacijskih krivulj. Za izbrano jeklo, v že prej omenjenem korozivnem mediju, sta njuni vrednosti sledeči; c> 0,125 M NaCl, ter T = 40 °C. Z naraščajočo temperaturo se Epp pomika proti negativnejšim vrednostim. Odvisnost Epp z 1/T daje linearno zvezo, razen v neposredni bližini CIC in CTP, kjer premica spremeni naklon. Predvideli smo, da to območje predstavlja okvirno mejo med "metastabilnim in stabilnim pittingom".Source: Jubilejni 10. Slovenski kemijski dnevi 2004, Maribor, 23. in 24. september 2004 [Elektronski vir] (8 str.)Type of material - conference contributionPublish date - 2004Language - slovenianCOBISS.SI-ID - 9013014
Author
Fuchs-Godec, Regina
Topics
elektrokemija |
avstenitna jekla |
točkasta korozija |
koncentracija kloridnih ionov |
kritična temperatura točkaste korozije |
metastabilna točkasta korozija |
austenitic stainless steel |
critical ion (Cl-) concetration |
critical pitting corrosion temperature |
metastable pitting
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Fuchs-Godec, Regina | 08762 |
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