Priprava jodidne ionselektivne elektrode s kemijsko obdelavo bakrene žice
Kolar, Mitja, kemik ; Gros, Igor ; Dobčnik, Danilo
Opisujemo enostavno pripravo jodidne ionoselektivne elektrode s kemijsko obdelavo sulfidizirane bakrene žice v raztopini kalijevega jodida. Elekroda je odzivna na ▫$Cu^{2+}$▫ ione ter daje linearen ...odziv v koncentracijskem območju med ▫$10^{-2}$▫ in 1x▫$10^{-5}$▫ ▫$molL^{-1}$▫ za bakrove ione s strmino 31 ▫$mV(pCu)^{-1}$▫, v koncentracijskem območju jodida pa med ▫$10^{-2}$▫ in 3x▫$10{-5}$▫ ▫$molL^{-1}$▫ s strmino 62 ▫$mV(pJ)^{-1}$▫. Podatki dobljeni pri površinski analizi elektrodne površine potrjujejo in dopolnjujejo razlago potenciometričnih lastnosti te ionoselektivne elektrode.
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