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Xie, Lilia S; Alexandrov, Eugeny V; Skorupskii, Grigorii; Proserpio, Davide M; Dinc, Mircea
Chemical science, 09/2019, Volume: 1, Issue: 37Journal Article
We report three electrically conductive metal-organic frameworks (MOFs) based on a tetrathiafulvalene linker and La 3+ . Depending on the solvent ratios and temperatures used in their solvothermal synthesis, these MOFs crystallize with different topologies containing distinct π-π stacking sequences of the ligand. Notably, their transport properties correlate rationally with the stacking motifs: longer S S contact distances between adjacent ligands coincide with lower electrical conductivities and higher activation energies. Diffuse reflectance spectroscopic measurements reveal ligand-based intervalence charge transfer bands in each phase, implicating charge delocalization among mixed-valent tetrathiafulvalene units as the dominant mode of transport. Overall, these frameworks demonstrate how tuning the intermolecular interactions in MOFs serves as a route towards controlling their physical properties. We report three electrically conductive metal-organic frameworks (MOFs) based on a tetrathiafulvalene linker and La 3+ .
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