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Bianco, Alberto; Zaffagnini, Mirko; Bergamini, Giacomo
Sustainable energy & fuels, 09/2022, Volume: 6, Issue: 19Journal Article
A strongly photoreducing ruthenium complex has been used to regenerate nicotinamide cofactor with only visible light and l -cysteine. The photoinduced processes have been deeply characterized, and the emission of NADH has been employed for the assessment of selectivity towards the enzymatically active photoregenerated cofactor. An aged Ru complex has been successfully employed for the photochemical monoreduction of NAD + achieving mediator-free NADH formation with the only aid of l -cysteine and visible light.
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