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Zhang, Qiaobao; Zhao, Bote; Wang, Jiexi; Qu, Chong; Sun, Haibin; Zhang, Kaili; Liu, Meilin
Nano energy, October 2016, 2016-10-00, Volume: 28Journal Article
Mixed transition metal oxides with hierarchical, porous structures, constructed from interconnected nano-building blocks, are considered promising positive electrodes for high-performance hybrid supercapacitors. Here we report our findings in design, fabrication, and characterization of 3D hierarchical, porous quaternary zinc-nickel-aluminum-cobalt oxide (ZNACO) architectures assembled from well-aligned nanosheets grown directly on nickel foam using a facile and scalable chemical bath deposition process followed by calcination. When tested as a binder-free electrode in a 3-electrode configuration, the ZNACO display high specific capacity (839.2Cg−1 at 1Ag−1) and outstanding rate capability (~82% capacity retention from 1Ag−1 to 20Ag−1), superior to those of binary-component NiCo2O4 and ZnCo2O4 as well as single-component Co3O4 electrode. More remarkably, a hybrid supercapacitor consisting of an as-fabricated ZNACO positive electrode and an activated carbon negative electrode exhibits a high energy density of 72.4Whkg−1 at a power density of 533Wkg−1 while maintaining excellent cycling stability (~90% capacitance retention after 10,000 cycles at 10Ag−1), demonstrating a promising potential for development of high-performance hybrid supercapacitors. Further, the unique electrode architecture is also applicable to other electrochemical systems such as batteries, fuel cells, and membrane reactors. Display omitted •3D hierarchical porous Zn-Ni-Al-Co oxide (ZNACO) nanosheets grown directly on Ni foam is constructed for the first time.•The resultant binder-free electrodes manifest outstanding electrochemical performances with high capacity, excellent rate capability and cycling stability.•The synergetic contribution and advantageously structural features contribute to outstanding capacitive performance.•The assembled ZNACO//AC hybrid supercapacitor achieved a remarkable energy density of 72.4Whkg−1 at a power density of 533Wkg−1.
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