VSE knjižnice (vzajemna bibliografsko-kataložna baza podatkov COBIB.SI)
  • A carbonate-templated decanuclear mn nanocage with two different silsesquioxane ligands
    Sheng, Kai ...
    The mild reaction of the preorganized silsesquioxane precursor with Mn(II) acetate under ambient conditions results in a mixed-valent {MnII 6MnIII4} nanocage (SD/Mn10) which is protected by both ... acyclic trimer [Si3] and cyclic tetramer [Si4]. Serendipitous capture of atmospheric CO2 as a μ5-carbonate anion placed at the center supports the formation of the cluster. The magnetic analysis reveals the strong antiferromagnetic interactions between Mn ions. Moreover, the dropcasting film of SD/Mn10 shows photoelectric activity indicating its great potential as a semiconductor for photoelectric conversion applications.
    Vir: Inorganic chemistry. - ISSN 0020-1669 (Vol. 60, no. 19, 2021, str. 14866-14871)
    Vrsta gradiva - članek, sestavni del ; neleposlovje za odrasle
    Leto - 2021
    Jezik - angleški
    COBISS.SI-ID - 124948227

vir: Inorganic chemistry. - ISSN 0020-1669 (Vol. 60, no. 19, 2021, str. 14866-14871)
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