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  • Wired porous cathode materials : a novel concept for synthesis of ▫$LiFePO_4$▫
    Dominko, Robert ...
    To increase the power density of battery materials, without significantly affecting their main advantage of a high energy density, novel material architectures need to be developed. Using the example ... of LiFePO4, we demonstrate a simple, sol-gel-based route that leads to large (up to 20 m) primary LiFePO4 particles, each of which contains hierarchically organized pores in the meso and macro range. As the pores are formed due to vigorous gas evolution (mainly CO and CO2) during degradation of a citrate precursor, they are perfectly interconnected within each particle. Elementary carbon, the other citrate-degradation product, is deposited on the walls of emerging pores. The superposition of a continuous 1-2 nm thick carbon film (electron conductor) on pores (ion conductor when filled with electrolyte) represents a unique architecture in which the electrons and ions are simultaneously supplied to the site of insertion in the particle interior. The material can operate at current rates up to 50 C while preserving a high tap density of ca.1.9 g cm-3.
    Vir: Chemistry of materials. - ISSN 0897-4756 (Vol. 19, no. 12, 2007, str. 2960-2969)
    Vrsta gradiva - članek, sestavni del
    Leto - 2007
    Jezik - angleški
    COBISS.SI-ID - 3707674

vir: Chemistry of materials. - ISSN 0897-4756 (Vol. 19, no. 12, 2007, str. 2960-2969)
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