VSE knjižnice (vzajemna bibliografsko-kataložna baza podatkov COBIB.SI)
  • Impact on Hydrogenation Catalytic Cycle of the R Groups' Cyclic Feature in "R-SMS-Phos"
    Zupančič, Borut, 1981- ; Mohar, Barbara ; Stephan, Michel
    A series of R-SMS-Phos ligands was evaluated in the Rh(I)-catalyzed hydrogenation of a set of olefins showing a marked influence of the cyclic nature and structure of the R groups. Overall, cPen- and ... Cy-SMS-Phos performedefficiently, while Ph- and Bn-SMS-Phos exhibited slower kinetics and furnished lower eećs also compared with C6F5CH2-SMS-Phos. The Rh(I)-(Cy-SMS-Phos) catalyst was screened under mild conditions displaying excellent enantioselectivities and high TOFs. Cases of catalysis under catalyst or substrate control were identified.
    Vir: Organic letters. - ISSN 1523-7060 (Vol. 12, no. 13, 2010, str. 3022-3025)
    Vrsta gradiva - članek, sestavni del
    Leto - 2010
    Jezik - angleški
    COBISS.SI-ID - 4447514
    DOI

vir: Organic letters. - ISSN 1523-7060 (Vol. 12, no. 13, 2010, str. 3022-3025)
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