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  • Understanding ▫$^6Li$▫ MAS NMR spectra of ▫$Li_2MSiO_4$▫ materials (M=Mn, Fe, Zn)
    Mali, Gregor, 1971-2023 ...
    Analysis of 6Li MAS NMR spectra of several lithium transition-metal orthosilicates (Li2MSiO4, M=Mn, Fe, Zn) improved the understanding of the relation between the spectral parameters and the ... structural characteristics of the materials. It was shown that for manganese- and iron-containing materials the width of the 6Li spinning-sideband powder patterns can be roughly related to the arrangement of the transition-metal cations within the first cation coordination sphere around lithium. In mixed zinc-manganese lithium orthosilicates the 6Li isotropic shift depends on the number of Li-O-Mn bonds, in which a particular lithium site is involved. Each bond contributes a small negative Fermi-contact hyperfine shift of about -20 to -40ppm. The precise values of the contributions cannot be easily related to the geometry of the bonds. In iron-containing materials the isotropic shifts are composed of two contributions, the hyperfine shift and the pseudo-contact shift. The latter depends on the anisotropy of the magnetic susceptibility of the material. The magnetic properties of the iron-containing lithium orthosilicates are responsible also for very broad lines within their 6Li MAS NMR spectra. Pure zinc-lithium orthosilicate exhibits a narrow 6Li MAS NMR isotropic signal and no spinning-sideband powder pattern.
    Vir: Solid State Nuclear Magnetic Resonance. - ISSN 0926-2040 (Vol. 42, 2012, str. 33-41)
    Vrsta gradiva - članek, sestavni del
    Leto - 2012
    Jezik - angleški
    COBISS.SI-ID - 4809754

    Povezava(-e):

    http://www.sciencedirect.com/science/article/pii/S0926204011001007
    DOI

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