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  • Structural changes of open-framework calcium-terephthalate upon hydrothermal treatment
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    A new open-framework Ca-terephthalate was prepared solvothermally in a mixture water and N,N -dimethylformamide (DMF) using Ca(N03)2 4H20 and terephthalic acid (BDC) as precursors. The as-synthesised ... Ca(BDC)(H20)(DMF) material contains infinite chains of edge-sharing 8-fold Ca-polyhedra connected with terephthalate linkers. The material retains its framework structure after removal of solvent molecules from the pores and show fully reversible structure changes upon hydration/dehydration treatment.
    Vrsta gradiva - prispevek na konferenci
    Leto - 2011
    Jezik - angleški
    COBISS.SI-ID - 4821530