VSE knjižnice (vzajemna bibliografsko-kataložna baza podatkov COBIB.SI)
  • Increase of both order and disorder in the first hydration shell with increasing solute polarity
    Godec, Aljaž ; Smith, Jeremy C. ; Merzel, Franci
    Monte Carlo simulations of a small model solute in an aqueous solution are used to examine the effects of solute polarity on hydration structure. A judicious definition of the orientational order ... parameter leads to reinterpretation of the conventional picture of hydration. As the solute varies from hydrophobic to hydrophilic the ordered first shell water simultaneously fractionates into a more highly ordered and a more disordered component. The hydrogen-bond network rearranges such that the more ordered component relaxes to configurations of optimal intermolecular angles, the other fraction being released from the network.
    Vir: Physical review letters. - ISSN 0031-9007 (Vol. 107, iss. 26, 2011, str. 267801-1 - 267801-5)
    Vrsta gradiva - članek, sestavni del
    Leto - 2011
    Jezik - angleški
    COBISS.SI-ID - 4872474

    Povezava(-e):

    http://prl.aps.org/abstract/PRL/v107/i26/e267801

vir: Physical review letters. - ISSN 0031-9007 (Vol. 107, iss. 26, 2011, str. 267801-1 - 267801-5)
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Vnos na polico