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Water-soluble highly charged fullerene derivatives as spherical electrolytes. Electrostatic contributions to thermodynamic functions of systems containing mixtures of counterions differing in charge and sizeŠkerjanc, JožeThe Poisson-Boltzmann equation has been solved to obtain the electrostatic potential for the spherical cell model of a fullerene molecule at which charged functional groups are attached. The ... fullerene macroion is surrounded by mixtures of small counterions differing in size and charge. The electrostatic internal and free energies, degree of binding of counterions, osmotic coefficient, and distribution of counterions around the charged fullerene shell are calculated. These properties are presented as functions ofradii, charges and mole fractions of counterions.Vir: Acta chimica slovenica. - ISSN 1318-0207 (Letn. 53, št. 3, 2006, str. 331-337)Vrsta gradiva - članek, sestavni delLeto - 2006Jezik - angleškiCOBISS.SI-ID - 27967749
Avtor
Škerjanc, Jože
Teme
fizikalna kemija |
vodne raztopine |
raztopine elektrolitov |
elektrolitske raztopine |
sferični celični model raztopin |
termodinamika |
termodinamske funcije |
Poisson-Boltzmann-ova enačba |
fulerenitne lastnosti |
elektrostatski potencial |
osmozni koeficient |
fulereni |
fulerenski elektroliti |
fulerenheksmalonska kislina C66 |
protiioni |
Poisson-Boltzmann equation |
spherical cell model |
thermodynamic functions |
polyelectrolyte solutions |
fullerene electrolytes |
fullerenehexamalonic acid
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Škerjanc, Jože | 00870 |
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