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  • High temperature superelast...
    Zhang, Jian; Chen, Tong; Li, Wei; Bednarcik, Jozef; Dippel, Ann-Christin

    Materials & design, August 2020, 2020-08-00, 2020-08-01, Letnik: 193
    Journal Article

    Great interests on high temperature shape memory alloys (HTSMAs) are recently raised, driven primarily by the aerospace and automotive industries, for their potential to serve as solid state actuators at high temperatures over 373 K. Near equiatomic Ti-Ni conventional SMAs, as the most applied SMA system, were considered to possess appreciable shape memory effect and superelasticity only below 373 K, which owes to low martensitic transformation temperatures. Here we utilized the martensite stabilization effect and successfully expanded the viable zone of B19′ (monoclinic) martensite to 616 K in a 35% cold-rolled Ti-50Ni (CR35) SMA. After a training cycle, it exhibited quasi-linear superelasticity of narrow hysteresis, ~3% superelastic strain and high strength over 1.2 GPa in a wide temperature range up to 483 K. It is the first exploration of high temperature superelasticity associated with the stabilized martensite. Using transmission electron microscopy and in-situ heating/tensile synchrotron X-ray diffraction, we reveal the origin of martensite stabilization and the underlying mechanisms of unique superelasticity in the CR35. Our work provides an attractively facile approach to realize high temperature superelasticity in Ti-Ni conventional SMAs, as well as in other kinds of SMAs, for precise actuation within an expanded range of working temperature and stress. Display omitted •High temperature superelasticity associated with stabilized martensite was achieved upto 483K in 35% cold rolled Ti-50Ni.•Superelasticity possesses quasi-linearity of narrow hysteresis, 3% strain and >1.2GPa strength in 185K temperature range.•Martensite stabilization in severely deformed Ti-50Ni is attributed to biased local stress fields of dislocation network.•Superelasticity originates from elasticity, reversible stress-induced B2➔B19’ transition and reorientation of B19’ domains.•We provide a facile approach to expand the working temperature and stress zones of superelasticity in shape memory alloys.