Amorphous carbon (a-C) film about 3 μm in thickness is coated on 316L stainless steel by close field unbalanced magnetron sputter ion plating (CFUBMSIP). The AFM and Raman results reveal that the a-C coating is dense and compact with a small size of graphitic crystallite and large number of disordered band. Interfacial contact resistance (ICR) results show that the surface conductivity of the bare SS316L is significantly increased by the a-C coating, with values of 8.3–5.2 mΩ cm 2 under 120–210 N/cm 2. The corrosion potential ( E corr) shifts from about −0.3 V vs SCE to about 0.2 V vs SCE in both the simulated anode and cathode environments. The passivation current density is reduced from 11.26 to 3.56 μA/cm 2 with the aid of the a-C coating in the simulated cathode environment. The a-C coated SS316L is cathodically protected in the simulated anode environment thereby exhibiting a stable and lower current density compared to the uncoated one in the simulated anode environment as demonstrated by the potentiostatic results.