Central Technological Library of the University of Ljubljana (CTK)
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Alkali vapour pressure variations during ▫$Na_2KSb(Cs)$▫ photocathode synthesisErjavec, BojanA highly efficient semi-transparent multialkali antimonide ▫$Na_2KSb(Cs)$▫ photocathode was synthesized in situ by a standard procedure. The synthesis steps leading to p-doping of the ▫$Na_2KSb$▫ ... base layer, the creation of n-type K and Cs surface states, the creation of a Cs surface dipole layer and, finally to the formation of Cs-Sb surface dipole layer or incorporation of Cs and Sb into an n-type surface compound are identified and explained. The addition and substitution reactions of alkali (sub) antimonide compounds, taking place during the synthesis of the homogeneous base layer, are considered thermodynamically using fairly reliable estimates of thermochemical functions. Alkali vapour pressure variations influencing the synthesis of the highly efficient photocathode are discussed. Excess Na in the residual atmosphere reacts with the evaporated Sb, giving an undoped heterogeneous base layer. Excess Cs reacts with the evaporating Sb, preventing strong p-doping of the base layer and leading to an unfavourable p-type ▫$Cs_3Sb$▫ saturated compound inthe surface layer.Source: Vacuum. - ISSN 0042-207X (Vol. 45, no. 5, 1994, str. 617-622)Type of material - article, component partPublish date - 1994Language - englishCOBISS.SI-ID - 18139141
Author
Erjavec, Bojan
Topics
synthesis reactions |
high-efficiency multalkali-automonide photocathodes |
growth mechanism |
strongly p-type base layer |
n-type surface states |
Cs and Cs-Sb surface dipole layers |
n-type surface compound |
Cs-Sb binary system |
Na-Sb and K-Sb binary systems |
equlibrium alkali vapour pressures
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Erjavec, Bojan | 05673 |
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