The Cenozoic succession in the Lower Kura Basin includes largely uniform, often carbonate-free mudstones. Because age dating of these sediments has proved difficult, the stratigraphy of the Cenozoic ...succession and the distribution of organic-rich strata are poorly known. A better understanding of the Cenozoic succession is not only important for petroleum-systems-analysis, but also for the understanding of the Cenozoic evolution of the Caucasus region. Therefore, bulk geochemical data (carbonate, TOC, sulphur, Rock-Eval) of 885 samples and biostratigraphic data were collected along seven outcrop profiles. This enabled the establishment of a continuous stratigraphic record from the Middle Eocene to the Late Miocene (Pontian). The study results show that potential source rocks are present in three stratigraphic units: the Middle Koun (Middle Eocene), Maikop Group (Oligo-Miocene) and Diatom Formation (Upper Miocene). The Middle Koun is about 100 m thick near the Caspian Sea and contains highly oil-prone sediments (2–24 wt% TOC; HI 300–577 mgHC/gTOC), which may generate 1.5 tHC/m2. The Maikop Group contains on average 1.8 wt% TOC, but is often gas-prone. Highly oil prone layers (2–5 wt% TOC; HI 300–450 mgHC/gTOC) are rare. Nevertheless, the Upper Maikop Formation may generate ∼2 tHC/m2. The Diatom Formation contains paper shales with high TOC contents (3–22 wt%) and HI values (350–770 mgHC/gTOC). The paper shale unit is more than 60 m thick near the Caspian Sea and can generate 3.8 tHC/m2. Previously it was thought that the Maikop Group had the highest petroleum potential, whilst Upper Miocene and Middle Eocene source intervals were overlooked. The Middle Eocene to Lower Oligocene succession in the Kura Basin is largely carbonate-free. In contrast, coeval successions elsewhere in the Caucasus region contain sediments with varying, but often high carbonate contents. Differences in carbonate content imply greater water depth during deposition in the Kura Basin.
•Cenozoic organic matter-rich rocks in Azerbaijan occur in three distinct stratigraphic units.•The Middle Eocene Middle Koun Member is a prolific, but overlooked, source rock capable of generating up to 1.5 tHC/m2.•The Oligo- Miocene Maikop Group contains moderate amounts of organic matter, but can still generate about 2 tHC/m2.•Upper Miocene paper shales in the Diatom Fm. contain a remarkably high petroleum potential and may generate 3.8 tHC/m2.•Water depth during Middle Eocene to Lower Oligocene time was higher in Azerbaijan than in other in other Caucasus areas.
Due to the peculiar combination of dental features characteristic for different squaliform families, the position of the Late Cretaceous genera Protoxynotus and Paraphorosoides within Squaliformes ...has long been controversial. In this study, we revise these genera based on previously known fossil teeth and new dental material. The phylogenetic placement of Protoxynotus and Paraphorosoides among other extant and extinct squaliforms is discussed based on morphological characters combined with DNA sequence data of extant species. Our results suggest that Protoxynotus and Paraphorosoides should be included in the Somniosidae and that Paraphorosoides is a junior synonym of Protoxynotus. New dental material from the Campanian of Germany and the Maastrichtian of Austria enabled the description of a new species Protoxynotus mayrmelnhofi sp. nov. In addition, the evolution and origin of the characteristic squaliform tooth morphology are discussed, indicating that the elongated lower jaw teeth with erected cusp and distinct dignathic heterodonty of Protoxynotus represents a novel functional adaptation in its cutting-clutching type dentition among early squaliform sharks. Furthermore, the depositional environment of the tooth bearing horizons allows for an interpretation of the preferred habitat of this extinct dogfish shark, which exclusively occupied shelf environments of the Boreal- and northern Tethyan realms during the Late Cretaceous.
•First evidence of Protoxynotus in the Tethyan realm.•Synonymy of Paraphorosoides and Protoxynotus.•Protoxynotus is an early representative of the Somniosidae.•Novel functional adaptation of dentition among early squaliform sharks.
The Paratethys area extends from Central Europe to the borders of the Caspian Sea in Central Asia and hosts a significant number of petroleum provinces, many of which have been charged by Eocene to ...Miocene source rocks of supra‐regional significance. These include highly oil‐prone Middle Eocene marls and limestones in the Eastern Paratethys (Kuma Formation and equivalents) which are several tens of metres thick. Estimates of the source potential index (SPI) indicate that the Kuma Formation in the northern Caucasus and the Rioni Basin (Georgia) may generate 1 to 2 tons of hydrocarbons per square metre (tHC/m2). This implies that the Kuma Formation may also be an important and additional source rock in the eastern Black Sea.
Oligocene and Lower Miocene pelitic rocks (Maikop Group and equivalents) are considered to be the most important source rocks in the Paratethys. Vertical variations in source potential record different stages of basin isolation that reached a maximum during the Early Oligocene (NP23) Solenovian Event. However major variations exist between different sub‐basins in the Central and the Eastern Paratethys. In the Central Paratethys, the highest quality source rocks occur in the Carpathian Basin where the Menilite Formation, several hundreds of metres thick, can generate up to 10 tHC/m2. Locally the Menilite Formation is about 1500 m thick and continues into the Lower Miocene. In these settings, the Menilite Formation can generate approximately 70 tHC/m2. In the Alpine Foreland Basin (Schöneck and Eggerding Formations) and the Pannonian Basin (Tard Clay Formation), oil‐prone source rocks are restricted to the Lower Oligocene. In the Eastern Paratethys, the best source rock intervals of the Maikop Group are typically associated with the Early Oligocene Solenovian Event. By contrast, with the exception of the Kura Basin in Azerbaijan, the potential of Upper Oligocene and Lower Miocene rocks is often limited. In total, the Maikop Group may generate up to 2 tHC/m2 in the North Caucasus area and 4 tHC/m2 in the Rioni Basin.
A particular source rock facies is found in the Western Black Sea where diatomaceous rocks with good oil potential accumulated in the Kaliakra Canyon during Early Miocene time. This facies may generate up to 8 tHC/m2, but is probably limited to shelf‐break canyons.
Middle and Upper Miocene rocks are the main source for oil and thermogenic gas in the Pannonian Basin System, and also contributed to thermogenic hydrocarbons in the Moesian Platform and the South Caspian Basin. In addition, Upper Oligocene and Miocene rocks are the source for microbial gas in several basins including the Alpine and Carpathian foredeeps.
The aim of this study was to evaluate the effect on oral health, at age 9 years, of daily oral supplementation with the probiotic Lactobacillus reuteri, strain ATCC 55730, to mothers during the last ...month of gestation and to children through the first year of life. The study was a single-blind, placebo-controlled, multicenter trial involving 113 children: 60 in the probiotic and 53 in the placebo group. The subjects underwent clinical and radiographic examination of the primary dentition and carious lesions, plaque and gingivitis were recorded. Saliva and plaque were sampled for determination of mutans streptococci (MS) and lactobacilli (LB) in saliva and plaque as well as salivary secretory IgA (SIgA). Forty-nine (82%) children in the probiotic group and 31 (58%) in the placebo group were caries-free (p < 0.01). The prevalence of approximal caries lesions was lower in the probiotic group (0.67 ± 1.61 vs. 1.53 ± 2.64; p < 0.05) and there were fewer sites with gingivitis compared to the placebo group (p < 0.05). There were no significant differences between the groups with respect to frequency of toothbrushing, plaque and dietary habits, but to intake of fluoride supplements (p < 0.05). There were no intergroup differences with respect to L. reuteri, MS, LB or SIgA in saliva. Within the limitation of this study it seems that daily supplementation with L. reuteri from birth and during the first year of life is associated with reduced caries prevalence and gingivitis score in the primary dentition at 9 years of age.
The Oligocene Ruslar Formation is a hydrocarbon source rock in the Kamchia Depression, located in the Western Black Sea area. Depositional environment and source potential of the predominantly ...pelitic rocks were investigated using core and cuttings samples from four offshore wells. In these wells the Ruslar Formation is up to 500
m thick. Based on lithology and well logs, the Ruslar Formation is subdivided from base to top into units I–VI. Dysoxic to anoxic conditions and mesohaline to euhaline salinities prevailed during deposition of the Ruslar Formation. Relatively high oxygen contents occurred during early Solenovian times (lower part of unit II), when brackish surface water favoured nannoplankton blooms and the deposition of bright marls (“Solenovian event”). Anoxic conditions with photic zone anoxia were established during late Oligocene times (units III and IV) and, probably, reflect a basin-wide anoxic event in the Eastern Paratethys during Kalmykian times. Organic carbon content in the Ruslar Formation is up to 3%. Autochthonous aquatic and allochthonous terrigenous biomass contribute to the organic matter. Relatively high amounts of aquatic organic matter occur in the lower part of the Ruslar Formation (units I and II) and in its upper part (unit VI). Diatoms are especially abundant in the lower part of unit VI. The kerogen is of type III and II with HI values ranging from 50 to 400
mgHC/gTOC. Units I and II (Pshekian, lower Solenovian) are characterized by a fair (to good) potential to produce gas and oil, but potential sources for gas and oil also occur in the Upper Oligocene units IV–VI.
The scientific borehole Baden-Sooss penetrates a succession of Badenian (Langhian, Middle Miocene) sediments at the type locality of the Badenian, the old brickyard Baden-Sooss in the Vienna Basin. ...The sedimentary succession of the 102-m-cored interval consists of more than 95% bioturbated, medium-to-dark gray marly shales with carbonate contents between 11 and 25% and organic carbon contents between 0.35 and 0.65%. Biostratigraphic investigations on foraminifera (mainly lower part of Upper Lagenid Zone) and calcareous nannoplankton (standard zone NN5) indicate an early Badenian (Langhian) age. Cycles in carbonate content, organic carbon content, and magnetic susceptibility have been identified by power spectra analysis. Correlations between the three variables are extremely significant. Using cross-correlation, periods around 40 m correlate significantly with the 100 kyr
−1
eccentricity cycle, the ∼20 m periods with the obliquity cycle, and the 15 to 11-m periods with both precession cycles. Wavelet transformation and decomposition of composite periodic functions were used to obtain the position of the cycle peaks in the profile. Cross-correlation with orbital cycles (La2004) dates the Baden-Sooss core between −14.379 ± 1 and −14.142 my ± 9 kyr.
PTSD rarely occurs on its own and opinions on the correlation between PTSD and its comorbidities are still divided.
To identify the comorbidity profile of psychiatric diagnoses in PTSD – affected war ...veterans and to determine the correlation with mental and health problems.
The experimental group consisted of 154 war veterans with combat-related PTSD. The control group was made of 77 veterans without PTSD. The study applied a general demographic questionnaire, the Harvard Trauma Questionnaire – Bosnia and Herzegovina version and the MINI.
A 97.4% of PTSD-diagnosed veterans satisfied criteria for other mental disorders and that 44.8% suffered chronic somatic problems. More frequently they suffered from current depressive episode (41.6%), past depressive episode (36.4%), depressive episode with melancholic features (36.4%), dysthymia (13.6%), panic disorder with agoraphobia (11.0%), generalized anxiety disorder (82.5%) alcohol abuse (34.4%) and suicidal ideation (26.0%).
The study showed that chronic PTSD in war veterans was almost always accompanied by multiple psychiatric and often somatic comorbidities.
The Oligocene to early Miocene fine-grained succession in the Eastern Carpathians includes, from base to top the Lower Menilite (LMM), Bituminous Marl (BMM), Lower Dysodilic Shale (LDSM), and Upper ...Dysodilic Shale (UDSM) members. These stratigraphic units, constituting the main hydrocarbon source rocks in the Eastern Carpathians, have been studied in an outcrop section to determine its depositional environment and hydrocarbon potential.
The LMM contains high amounts of TOC, but because of low thickness its source potential is limited. The organic matter of the overlying BMM is mainly derived from autochthonous marine organisms including bacterial biomass. TOC contents are moderate because of dilution by carbonate minerals. Calcareous nannoplankton dates the BMM into nannoplankton zones NP21-22. Salinity and redox conditions varied from reduced to slightly enhanced and from strictly anoxic to dysoxic. The LDSM contains carbonate-free black shale and sandstone beds deposited in a depositional lobe under anoxic conditions. Despite of high HI values, land plants form a significant part of the organic matter. Channel fill sediments form the top of the LDSM. The lower part of the early Miocene UDSM accumulated in a lobe, whereas its upper part represents a basin plain setting. MTTC ratios reflect a trend from slightly enhanced to slightly decreased normal marine salinity. The presence of aryl-isoprenoids suggests a temporary photic zone anoxia controlled by salinity variations. Both marine and terrestrial biomass contributed to the organic matter. A major change towards oxic conditions occurred at the boundary between the UDSM and the overlying Gura Soimului Formation.
The studied succession can generate 6 t of hydrocarbons per square meter. All members are oil prone, but yield oil with different biomarker characteristics. This allows the identification of oil generated from different lithostratigraphic units.
•Source potential of Oligo-Miocene rocks in E′ Carpathians has been investigated.•Oligo-Miocene rocks are able to generate 6 tons of hydrocarbons per m2.•Considerable vertical variations of source potential of Oligo-Miocene rocks exist.•Links between depositional environment and source rock quality are highlighted.•Parameters to distinguish oil from different Oligo-Miocene units are presented.
Significant synchronous shifts in the chemistry, mineralogy, grain sizes and color of the sediments at 6 m below sea floor (mbsf) at ODP Site 1195 on the Marion Plateau (NE Australia) are interpreted ...to reflect a major regional paleoceanographic change: the initiation of the southern province of the Great Barrier Reef (GBR). The onset of this massive carbonate production centre nearby resulted primarily in increased deposition of carbonate-rich sediments of neritic origin. Both sedimentation rate and terrigenous input record a coincident decline attributed to inshore trapping of materials behind the reefs. Our best estimate places the development of reef framework in the southern part of the GBR between 560 and 670 kyr B.P., based on an age model combining magnetostratigraphic and biostratigraphic data. The proposed estimation agrees with previous studies reporting an age between 500 and 930 kyr B.P., constraining more tightly their results. However, it does not support research placing the birth of the GBR in Marine Isotope Stage (MIS) 11 (∼
400 kyr), nor the theory of a worldwide modern barrier reef development at that time.
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