•A new approach for determining the settling velocity of microplastic particles.•Microplastic-fine sediment interaction through five settling velocity regions.•3D-numerical Modelling of microplastic ...transport in the tidal Weser river.•Higher probability of small microplastic to pass the estuary and reach the open sea.•Higher microplastic concentration in the estuarine turbidity zone.
Microplastic (MP) pollution is an important challenge for human life which has consequently affected the natural system of other organisms. Mismanagement and also careless handling of plastics in daily life has led to an accelerating contamination of air, water and soil compartments with MP. Under estuarine conditions, interactions with suspended particulate matter (SPM) like fine sediment in the water column play an important role on the fate of MP. Further studies to better understand the corresponding transport and accumulation mechanisms are required. This paper aims at providing a new modeling approach improving the MP settling velocity formulation based on higher suspended fine sediment concentrations, as i.e. existent in estuarine turbidity zones (ETZ). The capability of the suggested approach is examined through the modeling of released MP transport in water and their interactions with fine sediment (cohesive sediment/fluid mud). The model results suggest higher concentrations of MP in ETZ, both in the water column as well as the bed sediment, which is also supported by measurements. The key process in the modeling approach is the integration of small MP particles into estuarine fine sediment aggregates. This is realized by means of a threshold sediment concentration, above which the effective MP settling velocity increasingly approaches that of the sediment aggregates. The model results are in good agreement with measured MP mass concentrations. Moreover, the model results also show that lighter small MP particles can easier escape the ETZ towards the open sea.
ABSTRACT
We present multiwavelength observations and a model for flat-spectrum radio quasar (FSRQ) NVSS J141922−083830, originally classified as a blazar candidate of unknown type (BCU II object) in ...the Third Fermi-LAT AGN Catalog. Relatively bright flares (>3 magnitudes) were observed on 2015 February 21 (MJD 57074) and 2018 September 8 (MJD 58369) in the optical band with the MASTER Global Robotic Nettelescopes. Optical spectra obtained with the Southern African Large Telescopeon 2015 March 1 (MJD 57082), during outburst, and on 2017 May 30 (MJD 57903), during quiescence, showed emission lines at 5325 Å and at ≈3630 Å that we identified as the Mg ii 2798 Å and C iii 1909 Å lines, respectively, and hence derived a redshift $z$ = 0.903. Analysis of Fermi-Large Area Telescope (LAT) data was performed in the quiescent regime (5 yr of data) and during four prominent flaring states in 2014 February–April, 2014 October–November, 2015 February–March, and 2018 September. We present spectral and timing analysis with Fermi-LAT. We report a hardening of the gamma-ray spectrum during the last three flaring periods, with a power-law spectral index Γ = 2.0–2.1. The maximum gamma-ray flux level was observed on 2014 October 24 (MJD 56954) at (7.57 ± 1.83) × 10−7 ph cm−2 s−1. The multiwavelength spectral energy distribution (SED) during the 2015 February–March flare supports the earlier evidence of this blazar to belong to the FSRQ class. The SED can be well represented with a single-zone leptonic model with parameters typical of FSRQs, but also a hadronic origin of the high-energy emission cannot be ruled out.
A swirling jet in the quasar 1308+326 Britzen, S.; Qian, S.-J.; Steffen, W. ...
Astronomy and astrophysics (Berlin),
06/2017, Volume:
602
Journal Article
Peer reviewed
Open access
Context. Despite numerous and detailed studies of the jets of active galactic nuclei (AGN) on pc-scales, many questions are still debated. The physical nature of the jet components is one of the most ...prominent unsolved problems, as is the launching mechanism of jets in AGN. The quasar 1308+326 (z = 0.997) allows us to study the overall properties of its jet in detail and to derive a more physical understanding of the nature and origin of jets in general. The long-term data provided by the Monitoring Of Jets in Active galactic nuclei with Very Long Baseline Array (VLBA) experiments (MOJAVE)⋆⋆ survey permit us to trace out the structural changes in 1308+326 that we present here. The long-lived jet features in this source can be followed for about two decades. Aims. We investigate the very long baseline interferomety (VLBI) morphology and kinematics of the jet of 1308+326 to understand the physical nature of this jet and jets in general, the role of magnetic fields, and the causal connection between jet features and the launching process. Methods. Fifty VLBA observations performed at 15 GHz from the MOJAVE survey were re-modeled with Gaussian components and re-analyzed (the time covered: 20 Jan. 1995–25 Jan. 2014). The analysis was supplemented by multi-wavelength radio-data (UMRAO, at 4.8, 8.0, and 14.5 GHz) in polarization and total intensity. We fit the apparent motion of the jet features with the help of a model of a precessing nozzle. Results. The jet features seem to be emitted with varying viewing angles and launched into an ejection cone. Tracing the component paths yields evidence for rotational motion. Radio flux-density variability can be explained as a consequence of enhanced Doppler boosting corresponding to the motion of the jet relative to the line of sight. Based on the presented kinematics and other indicators, such as electric-vector polarization position-angle (EVPA) rotation, we conclude that the jet of 1308+326 has a helical structure, meaning that the components are moving along helical trajectories and the trajectories themselves are also experiencing a precessing motion. A model of a precessing nozzle was applied to the data and a subset of the observed jet feature paths can be modeled successfully within this model. The data till 2012 are consistent with a swing period of 16.9 yr. We discuss several scenarios to explain the observed motion phenomena, including a binary black hole model. It seems unlikely that the accretion disk around the primary black hole, which is disturbed by the tidal forces of the secondary black hole, is able to launch a persistent axisymmetric jet. Conclusions. We conclude that we are observing a rotating helix. In particular, the observed EVPA swings can be explained by a shock moving through a straight jet that is pervaded by a helical magnetic field. We compare our results for 1308+326 with other astrophysical scenarios where similar, wound-up filamentary structures are found. They are all related to accretion-driven processes. A helically moving or wound up object is often explained by filamentary features moving along magnetic field lines of magnetic flux tubes. It seems that a “component” comprises plasma tracing the magnetic field, which guides the motion of the radiating radio-band plasma. Further investigations and modeling are in preparation.
We present the results of a series of radio, optical, X-ray, and γ-ray observations of the BL Lac object S50716+714 carried out between April 2007 and January 2011. The multifrequency observations ...were obtained using several ground- and space-based facilities. The intense optical monitoring of the source reveals faster repetitive variations superimposed on a long-term variability trend on a time scale of ~350 days. Episodes of fast variability recur on time scales of ~60−70 days. The intense and simultaneous activity at optical and γ-ray frequencies favors the synchrotron self-Compton mechanism for the production of the high-energy emission. Two major low-peaking radio flares were observed during this high optical/γ-ray activity period. The radio flares are characterized by a rising and a decaying stage and agrees with the formation of a shock and its evolution. We found that the evolution of the radio flares requires a geometrical variation in addition to intrinsic variations of the source. Different estimates yield robust and self-consistent lower limits of δ ≥ 20 and equipartition magnetic field Beq ≥ 0.36 G. Causality arguments constrain the size of emission region θ ≤ 0.004 mas. We found a significant correlation between flux variations at radio frequencies with those at optical and γ-rays. Theoptical/GeV flux variations lead the radio variability by ~65 days. The longer time delays between low-peaking radio outbursts and optical flares imply that optical flares are the precursors of radio ones. An orphan X-ray flare challenges the simple, one-zone emission models, rendering them too simple. Here we also describe the spectral energy distribution modeling of the source from simultaneous data taken through different activity periods.
In addition to previously measured screening values, laboratory parameters at follow-up examinations and during the treatment periods both on active drug and placebo were included. ...a wide ...variability of laboratory parameters exceeding the upper limit of normal at screening and in HVs with normal values at screening and receiving placebo...
The prevalence of drug use among nightlife attendees needs to be accurately estimated to, for example, evaluate preventive interventions. This study tested the feasibility of using a breath-sampling ...device to estimate the prevalence of drug use among nightlife attendees. The study was conducted at five nightclubs and a large music festival in Stockholm, Sweden. Participants were invited to participate and microparticles in exhaled breath were sampled and analyzed for 47 compounds using a state-of-the-art analytic method that follows forensic standards. In addition, participants' breath alcohol concentration was measured and they were interviewed about demographics, drinking habits, and drug use. Of the people invited, 73.7% (n = 1223) agreed to participate, and breath samples were collected from 1204 participants. Breath sampling was fast and well-accepted by participants. 13 percent of participants tested positive for an illicit drug, but only 4.3% self-reported drug use during the last 48 h. The most common substances detected were cocaine, amphetamine, and MDMA. There was no agreement between self-reported and measured use of any drug. Breath sampling is a convenient method to test illicit drug use among a large number of participants at events, and can be used as an estimate of drug use prevalence.
Analysis of microplastics (MP) in environmental samples is an emerging field, which is performed with various methods and instruments based either on spectroscopy or thermoanalytical methods. In ...general, both approaches result in two different types of data sets that are either mass or particle number related. Depending on detection limits of the respective method and instrumentation the derived polymer composition trends may vary. In this study, we compare the results of hyperspectral Fourier-transform infrared (FTIR) imaging analysis and pyrolysis gas chromatography-mass spectrometry (Py-GC/MS) analysis performed on a set of environmental samples that differ in complexity and degree of microplastic contamination. The measurements were conducted consecutively, and on exactly the same sample. First, the samples were investigated with FTIR using aluminum oxide filters; subsequently, these were crushed, transferred to glass fiber filters, in pyrolysis cups, and measured via Py-GC/MS. After a general data harmonization step, the trends in MP contamination were thoroughly investigated with regard to the respective sample set and the derived polymer compositions. While the overall trends in MP contamination were very similar, differences were observed in the polymer compositions. Furthermore, polymer masses were empirically calculated from FTIR data and compared with the Py-GC/MS results. Here, a most plausible shape-related overestimation of the calculated polymer masses was observed in samples with larger particles and increased particle numbers. Taking into account the different measurement principles of both methods, all results were examined and discussed, and future needs for harmonization of intermethodological results were identified and highlighted.
Graphical abstract
• Multi-tracer approach for the identification and characterisation of nitrate sources in a lagoon environment was used. • Different nitrate pollution sources in the lagoon were identified. • ...Isotopes in nitrate and boron were applied to distinguish different anthropogenic pollution sources. • Atmospheric depositions (based on Δ17O analyses of nitrate) were recognized as additional nitrate source.
A multi-isotope approach has been used in the Marano lagoon (NE Italy) and parts of its catchment area to identify causes of increased NO3- pollution. The hydrogeochemical features of different water types and potential sources of NO3- were characterized using the isotopic composition of NO3- (δ15N, δ18O, and Δ17O) and other source-related species such as B (δ11B), water (δ2H and δ18O) and SO42- (δ34S and δ18O). Water samples from the lagoon, its tributary rivers, the groundwater up-welling line, groundwater, sewer pipes, and open sea water have been collected at quarterly intervals in the years 2009–2010. The results indicate that the NO3- load in the lagoon was not only derived from agricultural activities but also from other sources such as urban waste water, in situ nitrification and atmospheric deposition. The δ34S signature in the lagoon clearly denotes the largely prevailing origin of aqueous SO42- from seawater, and practically points to the absence of any appreciable redox process involving S species in the lagoon. It also supports the existence of a connection between the lagoon and the nearby Tagliamento river.
Tire wear particles (TWP) are assumed to be the most dominant source of environmental microplastics (MP). Besides rubber components around 60% of tires are additives such as filling material and ...various chemicals added for vulcanization. The inevitably released TWP in daily traffic are therefore considered a threat to the ecosystem. Nevertheless, published studies on MP mass loads often exclude elastomers. Data concerning composition and concentrations of TWP compared to prominent “traditional” MP polymers, such as polyethylene, polypropylene, poly(ethylene terephthalate) and poly(vinyl chloride), are missing. Identification and quantification of TWP was implemented in an existing pyrolysis-gas chromatography–mass spectrometry (Py-GC/MS) method for MP determination. An approach to differentiate between car and truck tire wear and to quantify their respective mass loads is presented. Complex environmental samples such as road dust, fresh water and marine sediments, blue mussels, and marine salts were partly retrospectively analyzed using Py-GC/MS. The results showed ratios of car to truck tire wear up to 16 to 1 and underline the dominance of car compared to truck tire wear mass loads in all analyzed samples. Even though some retrospective data sets might be affected by suboptimal density separation conditions (NaBr, ρ = 1.5 g/cm3), TWP concentrations in road dust clearly exceeded those of “traditional” MP (Ø 5 g TWP vs 0.3 g MP per kg road dust (dry weight). Samples included in this study, which were archived further away from TWP sources such as roads, reflected decreasing TWP concentrations (Ø 24 μg TWP vs. 107 μg MP per kg sediment (dry weight); Ø 126 μg TWP vs. 378 μg MP per kg marine salt) or were no longer present (blue mussels), while “traditional” polymers were still ubiquitously distributed.
Display omitted
•Quantification of tire wear particles in environmental samples with Py-GC/MS.•Differentiation between truck and car tire wear impact.•Car to truck tire wear ratio in environmental samples between 11:1 and 16:1.•TWP dominated in traffic influenced areas.•“Traditional” MP were omnipresent and prevailed in remote areas.
Detailed knowledge of the material properties and internal structures of frozen ground is one of the prerequisites in many permafrost studies. In the absence of direct evidence, such as in-situ ...borehole measurements, geophysical methods are an increasingly interesting option for obtaining subsurface information on various spatial and temporal scales. The indirect nature of geophysical soundings requires a relation between the measured variables (e.g. electrical resistivity, seismic velocity) and the actual subsurface constituents (rock, water, air, ice). In this work, we present a model which provides estimates of the volumetric fractions of these four constituents from tomographic electrical and seismic images. The model is tested using geophysical data sets from two rock glaciers in the Swiss Alps, where ground truth information in form of borehole data is available. First results confirm the applicability of the so-called 4-phase model, which allows to quantify the contributions of ice-, water- and air within permafrost areas as well as detecting solid bedrock. Apart from a similarly thick active layer with enhanced air content for both rock glaciers, the two case studies revealed a heterogeneous distribution of ice and unfrozen water within Muragl rock glacier, where bedrock was detected at depths of 20–25 m, but a comparatively homogeneous ice body with only minor heterogeneities within Murtèl rock glacier.
PDF
